[N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2 N′,O]dibutyltin(IV)
نویسندگان
چکیده
The Sn(IV) atom in the title compound, [Sn(C(4)H(9))(2)(C(18)H(11)BrN(2)O(3))], shows a distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination. One of the butyl chains is disordered over two sites in a 0.60 (1):0.40 (1) ratio.
منابع مشابه
[N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2 N′,O]dimethyltin(IV)
The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(18)H(11)BrN(2)O(3))], shows a distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination geometry, with an axial O-Sn-O angle of 155.27 (9)°. The presence of an intra-molecular O-H⋯N hydrogen bond between the amido N atom and hydr-oxy H atom in the Schiff base ligand helps to stabilize the overall mol-ecular structure.
متن کامل[N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2 N′,O]dicyclohexyltin(IV)
The environment at the Sn(IV) atom in the title compound, [Sn(C(6)H(11))(2)(C(18)H(11)BrN(2)O(3))], is distorted trigonal-bipyramidal, with the two cyclo-hexyl groups and the imino N atom forming the equatorial plane. The axial O-Sn-O angle is 155.97 (9)°. The presence of an intra-molecular O-H⋯N hydrogen bond in the Schiff base ligand helps to stabilize the overall structure.
متن کامل[N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2 N′,O 2]diphenyltin(IV)
The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(18)H(11)ClN(2)O(3))], is O,N,O'-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C(2)SnNO(2) trigonal-bipyramidal geometry [C-Sn-C = 125.7 (2)°]. The two phenyl rings are oriented at a dihedral angle of 55.2 (3)°. Intra-molecular O-H⋯N hydrogen bonding is present in the crystal str...
متن کامل[N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2 N′,O]dimethyltin(IV)
The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(18)H(11)ClN(2)O(3))], shows a trans-C(2)NO(2)Sn trigonal-bipyramidal coordin-ation; the axial O-Sn-O angle is 155.22 (5)°. The tridentate N'-(5-chloro-2-oxidobenzyl-idene)-3-hydr-oxy-2-naphthohydrazidate dianion is stabilized by an intra-molecular O-H⋯N hydrogen bond.
متن کاملDicyclohexyl{3-hydroxy-N′-[1-(2-oxidophenyl-κO)ethylidene]-2-naphthohydrazidato-κ2 N′,O}tin(IV)
In the title compound, [Sn(C(6)H(11))(2)(C(19)H(14)N(2)O(3))], the Sn(IV) atom is O,N,O' chelated by the deprotonated Schiff base ligand and exists in a cis-trigonal-bipyramidal environment, completed by the two cyclohexyl ligands.
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